Determination of the Atomic Weight of Cadmium

Synopsis

The method of weighing the more or less hygroscopic cadmium sulphate is open to criticism when employed in accurate work. The cadmium sulphate was placed in an open boat, dried, cooled over sulphuric acid, and weighed. It was again dried, cooled as before, and weighed. The second weighing could be quickly accomplished since the approximate weight was known. The two weighings agreed to within less than a milligram or a third drying and weighing were made. An error of a milligram in the weight of the sulphate produced an average error in the atomic weight of cadmium of about .06. That a discrepancy of greater or less magnitude was introduced from this source will be readily seen.

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